Product ID:S00602, SPRAYON ULTRA BLUE LAYOUT DYE
MSDS Date:08/14/2000
FSC:6850
NIIN:01-015-0834
Status Code:A
MSDS Number: CLBPX

THE SHERWIN-WILLIAMS CO- CONSUMER GROUP-INDUSTRIAL

CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 800-251-2486

Cage: UO384

THE SHERWIN-WILLIAMS CO- CONSUMER GROUP-INDUSTRIAL

CLEVELAND, OH 44115 US

Telephone: 800-251-2486

Cage: UO384

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1800 MG/M3;1000 PPM

ACGIH TLV: 2500 PPM

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 100 PPM (SKIN)

ACGIH TLV: 50 PPM (SKIN)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-PROPANOL

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 980 MG/M3;400 PPM

ACGIH TLV: 983 MG/M3;400 PPM

1-BUTANOL

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 50 PPM (SKIN) C

ACGIH TLV: 50 PPM (SKIN) C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ETHYL KETONE

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 590 MG/M3;200 PPM

ACGIH TLV: 590 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 50 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL 3-ETHOXYPROPIONATE

CAS: 763-69-9

RTECS: UF3325000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN, AND
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
CHRONIC: PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE
ADVERSE EFFECTS TO THE LIVER, URINARY, CARDIOVASCULAR AND
REPRODUCTIVE SYSTEMS. REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BR AIN AND
NERVOUS SYSTEM DAMAGE. METHYL ETHYL KEYTONE MAY INCREASE THE
NERVOUS SYSTEM EFFECTS OF OTHER SOLVENTS.
Explanation of Carcinogenicity:NO INGREDIENT IN THIS PRODUCT IS AN
IARC, NTP, OR OSHA LISTED CARCINOGEN.
Effects of Overexposure:EYE, SKIN, RESPIRATORY IRRITATION. NERVOUS
SYSTEM DEPRESSION. UNCONSCIOUSNESS AND POSSIBLY DEATH. HEADACHE,
DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND ITCHING
OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHALATION: MOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM
AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH
EYE S WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION. SWALLOWED: NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE CONSCIOUS PATIENT
SEVERAL G LASSES OF WATER. SEEK MEDICAL ATTENTION.

Flash Point:<-17.6C, 0.F
PROPELLANT
Lower Limits:1.0
Upper Limits:12.7
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY
BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER
MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE BUILDUP
AND POSSIBLE AUTOIGNITION OF EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL
PRECAUTIONS. DURING EMERGENCY C ONDITIONS OVEREXPOSURE TO
DECOMPOSITION PRODUCTS MAY CAUSE HEALTH HAZARD. SYMPTOMS MAY NOT BE
IMMEDIATELY APPARENT.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN
FLAMES. VAPORS WILL ACCUMULATE AND MAY IGNITE EXPLOSIVELY. KEEP
AREA VENTILLATED. DO NOT SMOKE. EXTINGUISH FLAMES, PILOT LIGHTS,
HEATERS. TURN OFF STOVES, ELECTRIC TO OLS, APPLIANCES, OTHER
SOURCES OF IGNITION. CONSULT NFPA CODE. USE BONDING AND GROUNDING
PROCEDURES.
Other Precautions:CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE,
OR EXPOSE TO TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS,
STOVES, HOT WATER, OTHER HEAT SOURCES COULD CAUSE CONTAINER TO
BURST. DO NOT T AKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
CONCENTRATING AND INHALING CAN BE HARMFUL OR FATAL.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION. WEAR A PROPERLY FITTED ORGANIC
VAPOR / PARTICULATE RESPIRATOR APPROVED BY NIOSH / MSHA FOR
PROTECTION AGAINST MATERIAL S IN INGREDIENTS.
Ventilation:LOICAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
Protective Gloves:NORMALLY NONE NEEDED. FOR LONG/REPEATED CONTACT, WEAR
CHEMICAL RESISTANT GLOVES
Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Work Hygienic Practices:USE ONLY WITH ADEQUATE VENTILATION. AVOID
BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES.
WASH HANDS AFTER USING.
Supplemental Safety and Health
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE
CONTENTS CAN BE HARMFUL OR FATAL.

HCC:V3
Boiling Pt:B.P. Text:<0 TO -342F (<-18-172C
Vapor Density:>AIR
Volatile Org Content %:95
Spec Gravity:0.76, (6.28 LB / GAL)
Evaporation Rate & Reference:>ETHER
Percent Volatiles by Volume:97

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER RESOURCE CONSERVATION AND RECOVERY ACT 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITIBILITY TO DETERMINE THE APPLICABLE
EPA HAZARDOUS WASTE NUMBE RS. DO NOT INCINERATE. DEPRESSURIZE
CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCA L
REGULATIONS REGARDING POLLUTION.

Toxicological Information:NO INGREDIENT IN THIS PRODUCT IS AN IRAC,
NTP, OR OSHA LISTED CARCINOGEN. METHYL ETHYL KETONE MAY INCREASE
THE NERVOUS SYSTEM EFFECTS OF OTHER SOLVENTS. PROLONGED
OVEREXPOSURE TO SOLVENT INGREDIENTS M AY CAUSE ADVERSE EFFECTS TO
THE LIVER, URINARY, CARDIOVASCULAR AND REPRODUCTIE SYSTEMS. REPORTS
HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION: TOLUENE, CAS# 108-88-3, TOLUENE, WT =14%; CAS#
1330-20-7, XYLENE, WT. = 3%; CAS# 71-36-3, 1-BUTANOL, WT.= 2%; CAS#
78-93-3, METHYLETHYL KETONE, WT.= 48 %; CAS# 108-10-1, METHYL
ISOBUTYL KETONE, WT.= 5%.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.